In a recent publication [Nauser et al. (2001) Chem. Res. Toxicol. 14, 248-350], the authors estimated a value of 14 +/- 3 kcal/mol for the standard Gibbs energy of formation of ONOO(-) and argued that the experimental value of 16.6 kcal/mol [Merényi, G., and Lind, J. (1998) Chem. Res. Toxicol. 11, 243-246] is in error. The lower value would suggest that the yield of free radicals during decomposition of ONOOH into nitrate is negligibly low, i.e., less than 0.5
作者:S, Goldstein;G, Czapski;J, Lind;G, Merényi
来源:Chemical research in toxicology 2001 年 14卷 6期