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Two phosphorescent Ir(III) complexes Ir(ppm)2(acac) and Ir(dmppm)2(acac) were synthesized and characterized with emission ranged at 584/600 nm and high photoluminescence quantum yields (PLQYs) of 0.90/0.92, respectively. The angle-dependent PL spectra analysis reveals that the two orange iridium(III) complexes embodied horizontal orientation property. The high photoluminescence quantum yield and high horizontal dipoles ratio determine their excellent device performance. The devices based on Ir(ppm)2(acac) and Ir(dmppm)2(acac) achieved efficiencies of 26.8

作者:Lin-Song, Cui;Yuan, Liu;Xiang-Yang, Liu;Zuo-Quan, Jiang;Liang-Sheng, Liao

来源:ACS applied materials & interfaces 2015 年 7卷 20期

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作者:
Lin-Song, Cui;Yuan, Liu;Xiang-Yang, Liu;Zuo-Quan, Jiang;Liang-Sheng, Liao
来源:
ACS applied materials & interfaces 2015 年 7卷 20期
标签:
horizontal orientation iridium complex orange emission organic light-emitting diodes pyrimidine warm-white
Two phosphorescent Ir(III) complexes Ir(ppm)2(acac) and Ir(dmppm)2(acac) were synthesized and characterized with emission ranged at 584/600 nm and high photoluminescence quantum yields (PLQYs) of 0.90/0.92, respectively. The angle-dependent PL spectra analysis reveals that the two orange iridium(III) complexes embodied horizontal orientation property. The high photoluminescence quantum yield and high horizontal dipoles ratio determine their excellent device performance. The devices based on Ir(ppm)2(acac) and Ir(dmppm)2(acac) achieved efficiencies of 26.8