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A facile approach for coating red fluoride phosphors with a moisture-resistant alkyl phosphate layer with a thickness of 50-100 nm is reported. K2 SiF6 :Mn(4+) particles were prepared by co-precipitation and then coated by esterification of P2 O5 with alcohols (methanol, ethanol, and isopropanol). This route was adopted to encapsulate the prepared phosphors using transition-metal ions as cross-linkers between the alkyl phosphate moieties. The coated phosphor particles exhibited a high water tolerance and retained approximately 87 

作者:Hoang-Duy, Nguyen;Chun Che, Lin;Ru-Shi, Liu

来源:Angewandte Chemie (International ed. in English) 2015 年 54卷 37期

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作者:
Hoang-Duy, Nguyen;Chun Che, Lin;Ru-Shi, Liu
来源:
Angewandte Chemie (International ed. in English) 2015 年 54卷 37期
标签:
light-emitting diodes phosphors photoluminescence white light
A facile approach for coating red fluoride phosphors with a moisture-resistant alkyl phosphate layer with a thickness of 50-100 nm is reported. K2 SiF6 :Mn(4+) particles were prepared by co-precipitation and then coated by esterification of P2 O5 with alcohols (methanol, ethanol, and isopropanol). This route was adopted to encapsulate the prepared phosphors using transition-metal ions as cross-linkers between the alkyl phosphate moieties. The coated phosphor particles exhibited a high water tolerance and retained approximately 87