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A nanoporous Ag-embedded SnO2 thin film was fabricated by anodic treatment of electrodeposited Ag-Sn alloy layers. The ordered nanoporous structure formed by anodization played a key role in enhancing the electrocatalytic performance of the Ag-embedded SnO2 layer in several ways: (1) the roughness factor of the thin film is greatly increased from 23 in the compact layer to 145 in the nanoporous layer, creating additional active sites that are involved in oxygen electrochemical reactions; (2) a trace amount of Ag (∼1.7 at

作者:Yang, Yang;Huilong, Fei;Gedeng, Ruan;Lei, Li;Gunuk, Wang;Nam Dong, Kim;James M, Tour

来源:ACS applied materials & interfaces 2015 年 7卷 37期

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作者:
Yang, Yang;Huilong, Fei;Gedeng, Ruan;Lei, Li;Gunuk, Wang;Nam Dong, Kim;James M, Tour
来源:
ACS applied materials & interfaces 2015 年 7卷 37期
标签:
SnO2 bifunctional electrocatalysts nanoporous oxygen evolution reaction oxygen reduction reaction silver-embedded tin oxide
A nanoporous Ag-embedded SnO2 thin film was fabricated by anodic treatment of electrodeposited Ag-Sn alloy layers. The ordered nanoporous structure formed by anodization played a key role in enhancing the electrocatalytic performance of the Ag-embedded SnO2 layer in several ways: (1) the roughness factor of the thin film is greatly increased from 23 in the compact layer to 145 in the nanoporous layer, creating additional active sites that are involved in oxygen electrochemical reactions; (2) a trace amount of Ag (∼1.7 at